The ReOX2L(PPh3) complexes (X = Cl or Br and L =N-methylsalicylideneiminate, N-phenylsalicylideneiminate, half N,N′-ethylenebis(salicylideneiminate) or 8-hydroxyquinolinate) react with dimethylphenylphosphine (PMe2Ph) to give ReOX2L(PMe2Ph) initially by displacement of the phosphine ligand and then the ReX2L(PMe2Ph)2 complexes with reduction of rhenium(V) to rhenium(III). The complexes were characterized by elemental analysis, magnetic susceptibility measurements and i.r. and1H n.m.r. spectra. © 1981 Verlag Chemie GmbH.
Reactivity of Schiff base rhenium(V) complexes with dimethylphenylphosphine
DUATTI, Adriano;
1981
Abstract
The ReOX2L(PPh3) complexes (X = Cl or Br and L =N-methylsalicylideneiminate, N-phenylsalicylideneiminate, half N,N′-ethylenebis(salicylideneiminate) or 8-hydroxyquinolinate) react with dimethylphenylphosphine (PMe2Ph) to give ReOX2L(PMe2Ph) initially by displacement of the phosphine ligand and then the ReX2L(PMe2Ph)2 complexes with reduction of rhenium(V) to rhenium(III). The complexes were characterized by elemental analysis, magnetic susceptibility measurements and i.r. and1H n.m.r. spectra. © 1981 Verlag Chemie GmbH.File in questo prodotto:
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