An efficient procedure for α-alkylation of cyclohex-2-enone and cyclopent-2-enone involving a base-promoted tandem of retrograde Dieckmann-Michael reactions of the C-alkylated derivatives of the title heterocycles is presented. © 1984.
2,3a,5,6,7,7a-Hexahydro-3H,4H-benzothiophene-3,4-dione and cyclopenta[b]tetrahydrothiophene-3,4-dione enolate anions as synthetic equivalents to cyclohex-2-enone and cyclopent-2-enone C-2-carbanions.
BARALDI, Pier Giovanni;BENETTI, Simonetta;POLLINI, Gian Piero;ZANIRATO, Vinicio
1984
Abstract
An efficient procedure for α-alkylation of cyclohex-2-enone and cyclopent-2-enone involving a base-promoted tandem of retrograde Dieckmann-Michael reactions of the C-alkylated derivatives of the title heterocycles is presented. © 1984.File in questo prodotto:
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