A perchlorate ligand in the rare µ4-1,1,2,2 binding mode is seen for the first time as the sole support for the assembly of two cationic [CuII2L]+ fragments (H3L = a dinucleating ligand) in the formation of a magnetically-exchanged tetranuclear cluster.
A novel [CuII4] cluster from the assembly of two [CuII2L]+ units by a central µ4-1,1,2,2 perchlorate ligand
BERTOLASI, Valerio;
2008
Abstract
A perchlorate ligand in the rare µ4-1,1,2,2 binding mode is seen for the first time as the sole support for the assembly of two cationic [CuII2L]+ fragments (H3L = a dinucleating ligand) in the formation of a magnetically-exchanged tetranuclear cluster.File in questo prodotto:
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