The addition of 2-trimethylsilylazoles (thiazole, benzothiazole, oxazole) to alfa-asymmetric aldehydes give the corresponding O-silylcarbinols in good chemical yield and high stereoselectivity: the reaction is employed for the steroselective homologation of D-glyceraldehyde
Diastereoselectivity in the 1,2-Addition of silylazoles to chiral aldehydes. Stereocontrolled homologation of alfa-hydroxyaldehydes
DONDONI, Alessandro;FOGAGNOLO, Marco;MEDICI, Alessandro;PEDRINI, Paola
1985
Abstract
The addition of 2-trimethylsilylazoles (thiazole, benzothiazole, oxazole) to alfa-asymmetric aldehydes give the corresponding O-silylcarbinols in good chemical yield and high stereoselectivity: the reaction is employed for the steroselective homologation of D-glyceraldehydeFile in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in SFERA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
