A new approach to long-chain sugars is demonstrated by the stereoselective conversion of D-glyceraldehyde acetonide , L-threose acetonide and dialdogalactopyranose diacetonide into higher homologues up to C9, C7 and C10 terms, respectively.
Iterative, stereoselective homologation of chiral polyalkoxyaldehydes employing 2-trimethylsilylthiazole as formyl anion equivalent. The thiazole route to the higher carbohydrates.
DONDONI, Alessandro;FANTIN, Giancarlo;FOGAGNOLO, Marco;MEDICI, Alessandro;PEDRINI, Paola
1989
Abstract
A new approach to long-chain sugars is demonstrated by the stereoselective conversion of D-glyceraldehyde acetonide , L-threose acetonide and dialdogalactopyranose diacetonide into higher homologues up to C9, C7 and C10 terms, respectively.File in questo prodotto:
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