The development of effective, cost-efficient, and printable solid-state gas sensors for the detection of volatile organic compounds is of great interest due to their wide range of applications, spanning from real-time indoor monitoring to emerging fields such as noninvasive medical diagnostics. However, gas sensors encounter difficulties in discovering materials that have both good selectivity and sensitivity for numerous volatile organic compounds in both dry and humid settings. To expand the class of sensing materials, the current study investigates the sensing performance of solid solutions based on a rare-earth metal oxide. Pr, Fe, and Ti oxide solid solutions were produced using a solid-state technique, with thermal treatments at varied temperatures to tune their structural and functional properties. The powders were used, for the first time, to produce chemoresistive sensors, which showed promising sensing capabilities vs. ethanol, acetone, and acetaldehyde. The sensors were characterized by varying the concentration of the target gases from 1 to 50 ppm in a controlled environment, with the relative humidity ranging from 2 to 40%. The findings bring a turning point, leading to fruitful paths for the development of Pr-based solid solutions-based chemoresistive gas sensors for the detection of volatile organic compounds.

PrFeTiO5-Based Chemoresistive Gas Sensors for VOCs Detection

Ahmed, Danial
Primo
;
Spagnoli, Elena
Secondo
;
Mancinelli, Maura;Fabbri, Barbara
Ultimo
2025

Abstract

The development of effective, cost-efficient, and printable solid-state gas sensors for the detection of volatile organic compounds is of great interest due to their wide range of applications, spanning from real-time indoor monitoring to emerging fields such as noninvasive medical diagnostics. However, gas sensors encounter difficulties in discovering materials that have both good selectivity and sensitivity for numerous volatile organic compounds in both dry and humid settings. To expand the class of sensing materials, the current study investigates the sensing performance of solid solutions based on a rare-earth metal oxide. Pr, Fe, and Ti oxide solid solutions were produced using a solid-state technique, with thermal treatments at varied temperatures to tune their structural and functional properties. The powders were used, for the first time, to produce chemoresistive sensors, which showed promising sensing capabilities vs. ethanol, acetone, and acetaldehyde. The sensors were characterized by varying the concentration of the target gases from 1 to 50 ppm in a controlled environment, with the relative humidity ranging from 2 to 40%. The findings bring a turning point, leading to fruitful paths for the development of Pr-based solid solutions-based chemoresistive gas sensors for the detection of volatile organic compounds.
2025
Ahmed, Danial; Spagnoli, Elena; Chakir, Adil; Mancinelli, Maura; Ferroni, Matteo; Mehdaoui, Boubker; Bouari, Abdeslam El; Fabbri, Barbara
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/2592677
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