Stable Ru-based catalysts containing unsym- metrical N-heterocyclic carbene (NHC) ligands with phenyl substituents on the backbone in syn and anti stereochemical relationships have been easily prepared and fully characterized. Preliminary investigation revealed that, depending on the backbone configuration, the new Ru complexes displayed different catalytic behaviors in representative olefin metathesis reactions.
Novel Olefin Metathesis Ruthenium Catalysts Bearing Backbone- Substituted Unsymmetrical NHC Ligands
BERTOLASI, Valerio;
2014
Abstract
Stable Ru-based catalysts containing unsym- metrical N-heterocyclic carbene (NHC) ligands with phenyl substituents on the backbone in syn and anti stereochemical relationships have been easily prepared and fully characterized. Preliminary investigation revealed that, depending on the backbone configuration, the new Ru complexes displayed different catalytic behaviors in representative olefin metathesis reactions.File in questo prodotto:
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