Electron ionization of sulphur-containing Nuphar alkaloids leads to the formation of easily detectable, doubly-charged species. The study of charge-separation reactions by collision experiments allows us to determine the intercharge distances. These experimental figures agree well with the different stereochemistries of the compounds under investigation.
Stereochemical Studies of Complex Molecules by Collisionally Induced Decomposition of Doubly Charged Ions. Nuphar Alkaloids
BORTOLINI, Olga;
1991
Abstract
Electron ionization of sulphur-containing Nuphar alkaloids leads to the formation of easily detectable, doubly-charged species. The study of charge-separation reactions by collision experiments allows us to determine the intercharge distances. These experimental figures agree well with the different stereochemistries of the compounds under investigation.File in questo prodotto:
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