By using a V(VI) or Mo(VI)-catalyzed two-phase procedure for oxybromination of organic substrates, adamantylideneadamantane bromonium salts (ADABr+X-; X- = V(V)- and Mo(VI)- containing anions) have been isolated and characterized. These salts proved to be significantly more stable relative to the corresponding tribromide derivative.
Direct Synthesis of Stable Adamantylideneadamantane Bromonium Salts
BORTOLINI, Olga;
1999
Abstract
By using a V(VI) or Mo(VI)-catalyzed two-phase procedure for oxybromination of organic substrates, adamantylideneadamantane bromonium salts (ADABr+X-; X- = V(V)- and Mo(VI)- containing anions) have been isolated and characterized. These salts proved to be significantly more stable relative to the corresponding tribromide derivative.File in questo prodotto:
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