Here we report a direct observation, by electrospray ionization mass spectrometry, of the intermediate [VO(OH2)(OH)- (OBr)]+, which may be involved in the catalytic cycle of the V-HalPO enzymes. Ab initio calculations also support the stability of such a species
Vanadium-Bromoperoxidase-Mimicking Systems: Direct Evidence of a Hypobromite-Like Vanadium Intermediate
BORTOLINI, Olga;
2003
Abstract
Here we report a direct observation, by electrospray ionization mass spectrometry, of the intermediate [VO(OH2)(OH)- (OBr)]+, which may be involved in the catalytic cycle of the V-HalPO enzymes. Ab initio calculations also support the stability of such a speciesFile in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in SFERA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
