Oxidation of p-XC6H4SOMe (X = NC, F3C) by (alkylperoxo)- {tris[(2R)-2-hydroxy-2-phenylethyl]amine}titanium (2b) has been shown to follow Michaelis−Menten kinetics demonstrating the occurrence of an intramolecular nucleophilic oxygen transfer to the TiIV-coordinated sulfoxide. The reaction of the titanium(IV) precursors 1 with sulfoxides has been studied by ESI-MS techniques together with ab initio calculations
On the Mechanism of the Oxygen Transfer to Sulfoxides by (Peroxo)[tris(hydroxyalkyl)amine]TiIV Complexes Evidence for a Metal-Template-Assisted Process
BORTOLINI, Olga;
2003
Abstract
Oxidation of p-XC6H4SOMe (X = NC, F3C) by (alkylperoxo)- {tris[(2R)-2-hydroxy-2-phenylethyl]amine}titanium (2b) has been shown to follow Michaelis−Menten kinetics demonstrating the occurrence of an intramolecular nucleophilic oxygen transfer to the TiIV-coordinated sulfoxide. The reaction of the titanium(IV) precursors 1 with sulfoxides has been studied by ESI-MS techniques together with ab initio calculationsFile in questo prodotto:
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