A mild and straightforward epoxidation protocol based on sodium perborate as primary oxidant and sodium dehydrocho-late as organomediator under homogeneous conditions is de-scribed. In particular, geraniol, linalool, 3-carene and -pinene are quantitatively converted into the corresponding 6,7-epoxides and trans-epoxides, respectively. The bile acid salt is recovered from the reaction mixture and may be re-used with unchanged efficiency and selectivity
A simple and efficient oxidation procedure for the synthesis of acid-sensitive epoxides
BORTOLINI, Olga;FANTIN, Giancarlo;FOGAGNOLO, Marco
2009
Abstract
A mild and straightforward epoxidation protocol based on sodium perborate as primary oxidant and sodium dehydrocho-late as organomediator under homogeneous conditions is de-scribed. In particular, geraniol, linalool, 3-carene and -pinene are quantitatively converted into the corresponding 6,7-epoxides and trans-epoxides, respectively. The bile acid salt is recovered from the reaction mixture and may be re-used with unchanged efficiency and selectivityFile in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in SFERA sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
