Current affairs: The electron-transport properties of a metal-molecule-metal junction based on two contacting redoxactive self-assembled monolayers of [Ru(NH3)5(NC5H 4-4-CH2NHCO(CH2)10-SH](PF 6)2 (see picture) is described. The junction becomes conductive when the electrode potentials are adjusted to the formal potential of the redox centers and shows diode- and transistor-like characteristics analogous to those of solid-state devices.
Electron transfer in a Hg-SAM//SAM-Hg junction mediated by redox centers
RAMPI, Maria Anita;
2004
Abstract
Current affairs: The electron-transport properties of a metal-molecule-metal junction based on two contacting redoxactive self-assembled monolayers of [Ru(NH3)5(NC5H 4-4-CH2NHCO(CH2)10-SH](PF 6)2 (see picture) is described. The junction becomes conductive when the electrode potentials are adjusted to the formal potential of the redox centers and shows diode- and transistor-like characteristics analogous to those of solid-state devices.File in questo prodotto:
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