Four O-perbenzylated glycosyl cyanides were converted by treatment with BrCH2CO2Et/Zn in THF at reflux (Blaise-Kishi reaction) into the corresponding C-glycosyl beta-enamino esters which in turn were reduced by NaBH(OAc)3 to give four pairs of C-glycosyl (R)- and (S)-beta-amino esters.

A facile and general entry to C-glycosyl (R)- and (S)-beta-amino acid pairs from glycosyl cyanides through enamino ester intermediates

DONDONI, Alessandro;MASSI, Alessandro;
2006

Abstract

Four O-perbenzylated glycosyl cyanides were converted by treatment with BrCH2CO2Et/Zn in THF at reflux (Blaise-Kishi reaction) into the corresponding C-glycosyl beta-enamino esters which in turn were reduced by NaBH(OAc)3 to give four pairs of C-glycosyl (R)- and (S)-beta-amino esters.
2006
Dondoni, Alessandro; Massi, Alessandro; Minghini, E.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11392/1201382
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