Our previous studies on 4-cyano- and 44methoxycarbonyl) thiolan-3-one, two sulfur-containing heterocycles usually utilized for the preparation of heteropolycyclic systems, led us to discover that their anions serve efficiently as synthetic equivalents of a-acrylate and a-acrylonitrile anions, respectively, allowing interesting synthetic application^.
Unusual Ring-Opening Reaction of 6,7-Dihydrothieno[3,2-d]pyrimidine- 2,4-dione Derivatives Leading to 5-(Alkylthio)-6-vinyluracils
BARALDI, Pier Giovanni;CACCIARI, Barbara;MANFREDINI, Stefano;POLLINI, Gian Piero;SIMONI, Daniele;ZANIRATO, Vinicio
1995
Abstract
Our previous studies on 4-cyano- and 44methoxycarbonyl) thiolan-3-one, two sulfur-containing heterocycles usually utilized for the preparation of heteropolycyclic systems, led us to discover that their anions serve efficiently as synthetic equivalents of a-acrylate and a-acrylonitrile anions, respectively, allowing interesting synthetic application^.File in questo prodotto:
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